Water splitting is a cornerstone technology for clean hydrogen production, and carbon-based electrocatalysts are leading the charge π. From pristine graphene, carbon nanotubes, and porous carbons to multidimensional nanostructures, these materials offer high conductivity, large surface area, and excellent chemical stability π¬. By tailoring defects, heteroatom doping (N, S, P, B), and nano-architectures, researchers enhance catalytic active sites, accelerating both hydrogen evolution (HER) and oxygen evolution reactions (OER) for efficient green energy systems π±.

To push performance further, scientists integrate carbon frameworks with advanced materials such as MOFs, POPs, and MXenes ⚙️. MOF-derived carbons provide tunable porosity and uniformly dispersed metal centers π§ͺ, while POP hybrids create robust, chemically stable networks with rich active sites π. MXene–carbon hybrids introduce metallic conductivity and surface terminations that improve charge transfer and catalytic kinetics ⚡. These hybrid strategies combine the best of each component, delivering superior activity, durability, and mass transport for next-generation electrocatalysts.
The evolution from pristine nanostructures to multifunctional hybrids marks a major leap in sustainable hydrogen technology π. Multidimensional carbon architectures enable faster electron flow, higher catalytic exposure, and long-term operational stability π. As research continues, engineering carbon-based electrocatalysts with MOF-, POP-, and MXene-integrations will unlock scalable, low-cost, and high-performance solutions for water splitting and future clean energy storage systems π§π.
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