π§ͺ A Review of Recent Coordination Chemistry and Catalytic Applications of Pyrazole & Pyrazolyl Complexes
π¬ Pyrazole and pyrazolyl ligands have become powerful building blocks in modern coordination chemistry due to their strong nitrogen-donor ability and structural versatility. These ligands easily bind with transition metals to form stable mono-, bi-, and polynuclear complexes. Their tunable electronic and steric properties allow chemists to design functional materials for catalysis, magnetism, and bioinorganic modeling, making them highly attractive in advanced chemical research.
⚗️ In catalytic chemistry, pyrazolyl transition-metal complexes show excellent performance in reactions such as C–C coupling, oxidation, hydrogenation, polymerization, and CO₂ activation. Metals like Fe, Cu, Ni, Co, and Pd combined with pyrazole frameworks enhance selectivity and reaction efficiency. These systems support green chemistry by lowering energy demands and improving catalyst recyclability.
π Recent advances highlight pyrazole complexes as key players in sustainable and industrial catalysis. Their stability, adaptability, and high reactivity open doors to applications in pharmaceuticals, materials science, and environmental chemistry. As research grows, pyrazolyl coordination chemistry continues to drive innovation in next-generation catalytic technologies. π
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